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Studies of adsorption and solution of acetylacetonates of Cr(III), Co(III) and Al(III) by gas chromatography
Authors:J Masłowska  S Starzyński
Institution:(1) Institute of General Food Chemistry, Technical University of Łódź, Stefanowskiego 4/10, 90-924 Łódź, Poland
Abstract:Summary Specific retention volumes, adsorption isotherms, molar heats of solution and changes of the entropy were determined from chromatographic data, which was obtained by the gas chromatographic separation of metal acetylacetonates. The retention data for Cr(III), Co(III) and Al(III) acetylacetonates were measured at different temperatures and different flow rates. From the retention data other values associated with adsorption and solution phenomena were calculated.
Keywords:Gas chromatography  Behaviour of metal acetylacetonates  Adsorption isotherms  Heat of solution
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