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One-pot Synthesis and Crystal Structure of (1S,2R,3S,4R,5S)-1-Phenyl-2,4-dibenzoyl-3,5-difurylhexanol
基金项目:广东省教育厅资助项目;广东省科技厅资助项目
摘    要:

关 键 词:取代环己醇  一壶合成  晶体结构  (1S,2R,3S,4R,5S)-1-苯基-2,4-联苯甲酰-3,5-二呋喃己醇

One-pot Synthesis and Crystal Structure of (1S,2R,3S,4R,5S)-1-Phenyl-2,4-dibenzoyl-3,5-difurylhexanol
CHEN Xiang-Ming,YIN Ye-Gao,CHEN He-Ru,DING Jun. One-pot Synthesis and Crystal Structure of (1S,2R,3S,4R,5S)-1-Phenyl-2,4-dibenzoyl-3,5-difurylhexanol[J]. Chinese Journal of Structural Chemistry, 2006, 25(6): 699-703
Authors:CHEN Xiang-Ming  YIN Ye-Gao  CHEN He-Ru  DING Jun
Affiliation:Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China
Abstract:(1S,2R,3S,4R,5S)-1-Phenyl-2,4-dibenzoyl-3,5-difurylhexanol 1 was synthesized by one-pot reaction of hypnone and furfurol in alkali H2O/EtOH solution and structurally defined to contain a chair-formed aliphatic carbocycle, on which the bulky substituents occupy the equatorial positions.
Keywords:substituted cyclohexanol  one-pot synthesis  crystal structure  hydrogen bond
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