Special features of photolytic transformation of tin heteropolymetallic catecholate complexes |
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| Authors: | E. V. Ilyakina O. G. Mishchenko A. V. Piskunov A. V. Maleeva S. V. Maslennikov I. V. Spirina V. P. Maslennikov Yu. A. Kurskii |
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| Affiliation: | 1.Research Institute of Chemistry,Lobachevskii State University,Nizhnii Novgorod,Russia;2.Razuvaev Institute of Organometallic Chemistry,Russian Academy of Sciences,Nizhnii Novgorod,Russia |
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| Abstract: | The photolysis of bis(dicarbonylcyclopentadienyliron)(3,6-di-tert-butylcatecholato)tin(IV), bis(dicarbonylcyclopentadienylmolybdenum)(3,6-di-tert-butylcatecholato)tin(IV), and bis(dicarbonylcyclopentadienyltunsten)(3,6-di-tert-butylcatecholato)tin(IV) in solutions of saturated hydrocarbons was studied. Kinetic parameters of the transformation of these compounds under the action of a monochromatic radiation with a wavelength of 313 nm were determined. Products of their transformation formed in the course of the irradiation were identified, and the probable mechanism of their photodecomposition was proposed. |
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