Chemistry of naphthazarin derivatives. 11. Trisubstituted hydroquinone derivatives in the preparative synthesis of naphthazarins |
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Authors: | Anufriev V Ph Polonik S G Pokhilo N D Balanyova N N |
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Institution: | (1) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation |
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Abstract: | The Friedel—Crafts acylation of trimethylhydroquinone, 3,5-diethyl-2-hydroxyhydroquinone, and 3,5-diethyl-1,2,4-trimethoxybenzene with dichloromaleic or citraconic anhydride in an AlCl3—NaCl melt is accompanied by o-C-dealkylation to afford functionally substituted naphthazarins. |
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Keywords: | hydroquinone derivatives dichloromaleic anhydride citraconic anhydride 5 8-dihydroxy-1 4-naphthoquinone naphthazarin the Friedel— Crafts reaction dealkylation |
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