Anodic oxidation of sodium 2-mercaptobenztiazolate anion in the presence of 5-methyl-2-hexanol |
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Authors: | E. E. Degtyareva A. B. Kilimnik I. A. Ankudimova |
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Affiliation: | (1) Tambov State Technical University, ul. Sovetskaya 106, Tambov, 392000, Russia |
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Abstract: | The anodic oxidation of the sodium 2-mercaptobenztiazolate anion in alkaline solution yields a finely dispersed difficultly filterable form of di-(2-benztiazolyl)disulfide, an accelerant of the rubber sulfur vulcanization. A crucial problem in the establishing of the continuous di-(2-benztiazolyl)disulfide electrosynthesis is the choice of reaction mixture, which ensures easy filtration of the target product. It was found by using oscillographic voltammetry at platinum microelectrode that the sodium 2-mercaptobenztiazolate anion in aqueous alkaline solution in the presence of 5-methyl-2-hexanol is oxidized to a radical that undergoes dimerization, thus yielding easily filterable form of di-(2-benztiazolyl)disulfide. The obtained result is explained by assuming that the dimer formation occurs in the 5-methyl-2-hexanol adsorption layer at the electrode surface. A reaction scheme of the process is suggested. |
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Keywords: | oscillographic voltammetry platinum microelectrode 2-mercaptobenztiazol 5-methyl-2-hexanol |
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