Carbonyl-inserted organo-hybrids of a Dawson-type phosphovanadotungstate: scope and chemoselective oxidation catalysis |
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| Authors: | Oble Julie Riflade Benoît Noël Amandine Malacria Max Thorimbert Serge Hasenknopf Bernold Lacôte Emmanuel |
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| Affiliation: | UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (UMR CNRS 7201), C. 229, 4 place Jussieu, 75005 Paris, France. |
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| Abstract: | The Dawson-type polyoxometalate (POM) [P(2)V(3)W(15)O(62)](9-) is a prototype for inclusion of carbonyls of amides, ureas, carbamates, and thiocarbamates into polyoxometallic structures. The carbonyl-inserted POMs catalyze the oxidation of sulfides. Chemoselectivity depends primarily on the proton content of the POM, but it is also influenced by the organic substituent. |
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