Ring cleavage and successive aldol reaction of 3-[(trialkylsilyl)methyl]cyclobutanones |
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| Authors: | Matsuo Jun-ichi Harada Kosuke Kawano Mizuki Okuno Ryosuke Ishibashi Hiroyuki |
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| Affiliation: | School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. |
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| Abstract: | 3-[(Trialkylsilyl)methyl]cyclobutanones reacted with aldehydes by activation with titanium(IV) chloride to give acyclic β,γ-unsaturated β'-hydroxyketones. |
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