Metal-free C-H cross-coupling toward oxygenated naphthalene-benzene linked biaryls |
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| Authors: | Dohi Toshifumi Ito Motoki Itani Itsuki Yamaoka Nobutaka Morimoto Koji Fujioka Hiromichi Kita Yasuyuki |
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| Institution: | College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu, Shiga 525-8577, Japan. |
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| Abstract: | The intermolecular C-H cross-coupling between aromatic ethers has been achieved for the first time using perfluorinated hypervalent iodine(III) compounds as extreme single-electron-transfer (SET) oxidants. The demonstrations of this specific coupling could provide a direct route to valuable oxygenated mixed naphthalene-benzene biaryls 3 only, without formation of other biaryl-derived byproducts. |
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