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Platinum(II) and platinum(IV) complexes of 2-amino-4, 6-dimethylpyrimidine
Authors:Dimitra Kovala-Demertzi
Institution:(1) Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
Abstract:Summary Platinum(II) and platinum(IV) complexes of 2-amino-4, 6-dimethylpyrimidine, ADMPY, have been prepared. Solids of formula Pt(ADMPYH+)Cl3, Pt(ADMPY)2Cl4 and Pt(ADMPY)2Cl4·2HCl have been isolated and characterized by elemental analyses in conjuction with i.r. and n.m.r. spectra. A paramagnetic tan to reddishbrown complex has been reproducibly prepared from the direct reaction of K2PtCl4 and ADMPY at pH 6.
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