| A Pseudo-Keggin Compound: Hydrothermal Synthesis and Crystal Structure of (DETAH)(DETAH_3)_3[V_(18)O_(42)(PO_4)]·(PO_4)·2H_2O |
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| 引用本文： | 相勇,张林雯,陈武华,陈建忠,曾庆新. A Pseudo-Keggin Compound: Hydrothermal Synthesis and Crystal Structure of (DETAH)(DETAH_3)_3[V_(18)O_(42)(PO_4)]·(PO_4)·2H_2O[J]. 结构化学, 2007, 26(4): 419-422 |
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| 作者姓名： | 相勇 张林雯 陈武华 陈建忠 曾庆新 |
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| 作者单位： | Department of Chemistry Fuzhou University，Department of Chemistry Fuzhou University，Department of Chemistry Fuzhou University，Department of Chemistry Fuzhou University，Department of Chemistry Fuzhou University，Fuzhou 350002 China，Fuzhou 350002 China，Fuzhou 350002 China，Fuzhou 350002 China，Fuzhou 350002 China |
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| 基金项目： | This work was supported by the Science and Technology Development Foundation of Fuzhou University (No.2004-xq-05)，the Scientific Research Foundation of Fujian Provincial Education Department (No. JB04010) |
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| 摘 要： | The novel vanadophosphate (DETAH)(DETAH3)3[V18O42(PO4)]·(PO4)·2H2O has been synthesized under hydrothermal conditions and its structure was determined by single-crystal X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 23.857(3), b = 12.9619(18), c = 20.204(3) , β = 105.692(2)°, V = 6015.0(14) 3, Z = 4, Dc = 2.473 g/cm3, Mr = 2239.68, F(000) = 4432, R = 0.0725, wR = 0.1524 and GOOF = 1.095. The metaloxo cluster contains a novel six-capped pesudo-Keggin structure unit which encloses a disorder PO43- guest.
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A Pseudo-Keggin Compound: Hydrothermal Synthesis and Crystal Structure of (DETAH)(DETAH_3)_3[V_(18)O_(42)(PO_4)]·(PO_4)·2H_2O |
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| XIANG Yong,ZHANG Lin-Wen,CHEN Wu-Hua,CHEN Jian-Zhong,ZENG Qing-Xin,. A Pseudo-Keggin Compound: Hydrothermal Synthesis and Crystal Structure of (DETAH)(DETAH_3)_3[V_(18)O_(42)(PO_4)]·(PO_4)·2H_2O[J]. Chinese Journal of Structural Chemistry, 2007, 26(4): 419-422 |
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| Authors: | XIANG Yong ZHANG Lin-Wen CHEN Wu-Hua CHEN Jian-Zhong ZENG Qing-Xin |
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| Abstract: | The novel vanadophosphate (DETAH)(DETAH3)3[V18O42(PO4)]·(PO4)·2H2O has been synthesized under hydrothermal conditions and its structure was determined by single-crystal X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 23.857(3), b = 12.9619(18), c = 20.204(3) , β = 105.692(2)°, V = 6015.0(14) 3, Z = 4, Dc = 2.473 g/cm3, Mr = 2239.68, F(000) = 4432, R = 0.0725, wR = 0.1524 and GOOF = 1.095. The metaloxo cluster contains a novel six-capped pesudo-Keggin structure unit which encloses a disorder PO43- guest. |
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| Keywords: | hydrothermal synthesis metal-oxo cluster pesudo-keggin structure six-capped |
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