Supraleitende Bleischichten mit Zusatz von Übergangsmetallen und ihren Oxiden

The influence of small additions of 3d-metals (Cr, Fe, Co) on the superconducting transition temperature of lead has been studied. Both components are condensed simultaneously on a quartz substrate, held at 10 °K. With this “Quench evaporation technique” we get a statistical distribution of the impurity atoms in the lead matrix. As in early experiments on In and Sn the superconducting transition temperature of Pb decreases linearly with increasing 3d-metal content. This is in agreement with the theoretical results ofAbrikosov-Gorkov andSkalski et al. For the first time an influence of 3d-metal oxides (Cr-, Mn- and Co-oxide) on the superconductivity of Pb has been found. The transition temperatureT _c decreases linearly with increasing oxide content (c) as in the case of the pure metals. For Mn and Co the slopesdT _c /dc are nearly equal for the pure metal and its oxide. In the case of Cr the influence of the oxide is about seven times greater than that of the pure metal. Furtheron it is shown by annealing experiments that the degree of precipitation has also an influence on the transition temperature in the system of lead with Fe, Co and CO₂O₃.