Macroheterocycles. 5. Synthesis of macrocyclic amido esters and amido thioesters on the basis of derivatives of α-hydroxy and α-mercapto acids |
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Authors: | N G Luk'yanenko A V Bogat-skii Yu A Popkov |
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Institution: | (1) Physicochemical Institute, Academy of Sciences of the Ukrainian SSR, 270080 Odessa |
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Abstract: | 3,6-Dioxa-4-keto-, 2-benzyl-3,6-dioxa-4-keto-, and 3-oxa-6-thio-5-ketooctanedioic acids were obtained by the reaction of diglycolic
acid anhydride with glycolic, β-phenyllactic, and thioglycolic acids. 2,9-Dibenzyl-3,8-dioxa-4,7-diketodecanoic acid was obtained
by the reaction of succinyl chloride with β-phenyllactic acid. Eight macrocyclic amido esters and amido thioesters that are
new polydentate macrocyclic ligands were synthesized by the reaction of the chlorides of the acids obtained with 3-oxa-1,5-diaminopentane,
3,6-dioxa-1,8-diaminooctane, and 1,4-diaminobutane.
See 1] for communication 4.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 306–309, March, 1980. |
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