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An expedient synthesis of salviadione |
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| Authors: | Matthew M CummingsRonald W Clawson Jr Sriganesh B SharmaRachel A Byerly Novruz G AkhmedovBjörn CG Söderberg |
| Institution: | C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, WV 26506-6045, USA |
| Abstract: | An expedient synthesis of the alkaloid salviadione, the only to date isolated naturally occurring 1H-benzodef]carbazole is described. The key step in the synthesis is a palladium-catalyzed, carbon monoxide-mediated reductive N-heterocyclization of a nitroarene with an adjacent alkene. |
| Keywords: | Palladium-catalyzed Reductive Cyclization Alkaloid Salviadione |
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