Impregnated palladium on magnetite, a new catalyst for the ligand-free cross-coupling Suzuki-Miyaura reaction |
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Authors: | Rafael CanoDiego J. Ramó n,Miguel Yus |
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Affiliation: | Instituto de Síntesis Orgánica (ISO), and Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Alicante, Apdo. 99, E-03080 Alicante, Spain |
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Abstract: | A new catalyst for the cross-coupling Suzuki-Miyaura reaction is reported. The impregnated palladium on magnetite catalyst is very easy to prepare using the standard impregnation methodology. This catalyst avoids the use of any type of expensive and difficult handle organic ligand, showing excellent yields, under mild reaction conditions, for the classical formation of biaryl compounds. The catalyst is very easy to remove from the reaction medium, only by using a simple magnet, and it could be re-used up to three times with only a slightly decrease of the chemical yield. |
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Keywords: | Biaryl Cross-coupling Heterogeneous Palladium Suzuki-Miyaura reaction |
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