Palladium-catalyzed asymmetric allylation and complex formation involving P,N-bidentate derivatives of (S)-2-(anilinomethyl)pyrrolidine |
| |
| Authors: | Bondarev O G Gavrilov K N Tsarev V N Davankov V A Lebedev R V Moiseev S K Kalinin V N |
| |
| Institution: | (1) Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) S. A. Esenin Ryazan State Pedagogic University, 46 ul. Svoboda, 390000 Ryazan, Russian Federation |
| |
| Abstract: | P,N-Bidentate (S)-2-(anilinomethyl)pyrrolidine derivatives and their complexes with rhodium(i) and palladium(ii) were synthesized. It was demonstrated that these compounds can be used in the Pd-catalyzed asymmetric allylation for the synthesis of chiral methyl 2-phenyl-2-(2-phenyl-o-carboranyl-1)pent-4-enoate. |
| |
| Keywords: | P N-ligands aminophosphites palladiun rhodium asymmetric synthesis allylation carboranes |
| 本文献已被 SpringerLink 等数据库收录！ |
