Contribution of adsorption to retention data in glass capillary gas chromatography part. I. Polar stationary phases |
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Authors: | J. Krupčik E. Matisová J. Garaj L. Soják V. G. Brezkin |
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Affiliation: | (1) Department of Analytical Chemistry, Faculty of Chemical Technology, Slovak Technical University, 81237 Bratislava, Czechoslovakia;(2) Chemical Institute, Comenius University, 81650 Bratislava, Czechoslovakia;(3) Topchiev's Institute of Petroleum Chemical Synthesis, Academy of Sciences, Lenin Avenue, 117334 Moscow, U.S.S.R. |
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Abstract: | Summary The influence of the film thickness of Carbowax 20M coated onto glass surfaces (series of columns with different mode of surface treatment) upon the retention indices of solutes which exhibit tendency to hydrogen bonding has been investigated. Limiting values of Kovats indices, I, are calculated for all the columns examined.Presented at the 14th International Symposium on Chromatography London, September, 1982 |
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Keywords: | Glass capillary columns Retention data Adsorption Influence of stationary phase film thickness |
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