Hydrolytic selenoxide elimination reaction for the preparation of 2-chloro-1-olefins |
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| Affiliation: | 1. School of Chemical Sciences, Mahatma Gandhi University, Kottayam 686 560, India;2. Department of Chemistry, St. Berchmans College, Changanassery 686 101, India |
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| Abstract: | 2-Chloro-1-olefins were synthesized in a regiocontrolled way from terminal olefins by a sequence involving Markownikoff-addition of PhSeCl, chlorination of the resulting β-chloroalkyl phenyl selenides with SO2Cl2 and, after recrystallization, hydrolysis/selenoxide elimination in a two-phase system. |
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