Etude de la chimioselectivite de la reaction des dichloroboranes avec les azides fonctionnels : une synthese efficace d'amines secondaires fonctionnalisees. |
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| Affiliation: | 1. Department of Chemistry, National University of Singapore, Singapore;2. Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong SAR, China;3. Shenzhen Municipal Key Laboratory of Chemical Synthesis of Medicinal Organic Molecules & Shenzhen Center of Novel Functional Molecules, Shenzhen Research Institute, The Chinese University of Hong Kong, Shenzhen, China;4. Department of Chemistry & State Key Laboratory of Synthetic Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong SAR, China |
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| Abstract: | The reaction of cyclohexyldichloroborane, used as a model, with a wide variety of functionalized azides has been studied. It has been shown to be an efficient synthesis of secondary amines in terms of chemioselectivity, yields and wide applicability. |
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