Preparation and X-ray crystal structure analysis of a stable trimethylsilyloxy epoxide |
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| Affiliation: | 1. Department of Chemistry, Zhejiang University, 866 Yuhangtang Road, Hangzhou 310058, PR China;2. School of Chemistry and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, PR China;1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;2. School of Technology and Physical Science, ShanghaiTech University, Shanghai 201210, China;1. Division of Synchrotron Radiation Research, Department of Physics, Lund University, Box 118, 22100 Lund, Sweden;2. Division of Pure & Applied Biochemistry, Lund University, Box 124, 22100 Lund, Sweden;3. ENI AB, Malmö, Sweden;4. Division of Solid State Physics, Department of Physics, Lund University, Box 118, 22100 Lund, Sweden |
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| Abstract: | Reaction of trimethylsilyl enol ether6 with buffered m-chloroperbenzoic acid at 20°C leads efficiently to7, the first shelf-stable silyloxy epoxide. The structural dimensions of7 have been ascertained by means of X-ray crystallography. |
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