A synthesis of 1,6-dioxaspiro[4.5]dec-3-enes. |
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Affiliation: | 1. Department of Food Science and Technology, Universidade Estadual de Londrina, Londrina, Paraná, Brazil;2. Department of Chemistry, Instituto Federal Catarinense – Câmpus Araquari, Araquari, Santa Catarina, Brazil |
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Abstract: | Base-catalysed rearrangement of a 2-alkynyl-tetrahydropyran generates an allenol ether intermediate which undergoes acid-catalysed cyclisation to the 1,6-dioxaspiro[4.5]dec-3-ene system. |
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