Electroreductive coupling of methallylchloride or methyl chloroacetate with carbonyl compounds catalyzed by nickel bipyridine complexes |
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| Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Uludag University, 16059 Bursa, Turkey;2. Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Samsun, Turkey;1. Kazan Federal University, Kremlyovskaya St., 18, Kazan 420008, Russian Federation;2. A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov St., Kazan 420088, Russian Federation |
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| Abstract: | An efficient electrosynthesis of homoallyl alcohols or β-hydroxy esters in the presence of catalytic amounts of the NiBr2(2,2′-bipyridine) complex has been developped from mixed electrolysis of methallylchloride, or methylchloroacetate with several carbonyl compounds, using a one-compartment cell equiped of a sacrificial zinc anode. |
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