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Reaction of the 1,3-phenylenediacetatodicopper(I) pyridine complex with dioxygen,hydrogen peroxide and carbon monoxide
Authors:Éva Balogh-Hergovich  Gábor Speier
Affiliation:(1) Research Group for Petrochemistry of the Hungarian Academy of Sciences and Department of Organic Chemistry, University of Veszprém, 8201 Veszprém, Hungary
Abstract:Summary The reactions of 1,3-phenylenediacetatodicopper(I) pyridine, prepared from 1,3-phenylenediacetatocopper(II) by metallic copper, were studied. On oxygenation, a copper-dioxygen complex was formed, whereas carbon monoxide yielded an unstable carbonyl complex. The complexes were characterised by spectroscopic measurements.
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