Reaction of the 1,3-phenylenediacetatodicopper(I) pyridine complex with dioxygen,hydrogen peroxide and carbon monoxide |
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Authors: | Éva Balogh-Hergovich Gábor Speier |
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Affiliation: | (1) Research Group for Petrochemistry of the Hungarian Academy of Sciences and Department of Organic Chemistry, University of Veszprém, 8201 Veszprém, Hungary |
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Abstract: | Summary The reactions of 1,3-phenylenediacetatodicopper(I) pyridine, prepared from 1,3-phenylenediacetatocopper(II) by metallic copper, were studied. On oxygenation, a copper-dioxygen complex was formed, whereas carbon monoxide yielded an unstable carbonyl complex. The complexes were characterised by spectroscopic measurements. |
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