Synthesis and characterization of Rh3(μ-PPh2)3(CO)3(PPh3)2: a novel triangular rhodium cluster |
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| Authors: | E Billig JD Jamerson RL Pruett |
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| Institution: | Chemicals and Plastics Division, Union Carbide Corporation, South Charleston, West Virginia 25303 U.S.A. |
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| Abstract: | Thermal decomposition of RhH(CO)(PPh3)3 (Ph = phenyl) in nonane at 120°C yielded a green solid in high yield. The complex was established as Rh3(μ-PPh2)3(CO)3(PPh3)2, (I), X-ray crystallography. I was found to be coordinately unsaturated in the solid state and in solution. |
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