On the kinetics of the inhibition of electrochemical homogeneous catalytic processes: Theory of the pulse-polarography and its application to the Fe-catalysed chlorite reduction,in the presence of EDTA acting as deactivator |
| |
| Authors: | Ph Buess L Gierst O Garcia de Alvarez |
| |
| Institution: | Faculté des Sciences, Université Libre de Bruxelles, C.P. 160 1050 Brussels (Belgium) |
| |
| Abstract: | A theory is developed for catalytic homogeneous processes inhibited by a bulk deactivation reaction in the case of a plane stationary electrode. The time-dependent diffusion equations, corrected for the kinetic terms, have been solved exactly using the Laplace transformation. The final equations have been successfully verified by studying the deactivation effect of EDTA on the reduction of chlorite ions, catalysed by the ferrate-ferrite couple. |
| |
| Keywords: | To whom correspondence should be addressed |
| 本文献已被 ScienceDirect 等数据库收录！ |
