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Synthesis and structure of a dimethyl(μ-hydrido)di-platinum(II) complex |
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| Authors: | Michael P Brown Susan J Cooper Aileen A Frew Ljubica Manojlović-Muir Kenneth W Muir Richard J Puddephatt Mary A Thomson |
| Institution: | Donnan Laboratories, The University of Liverpool, Liverpool L69 3BX Great Britain;Chemistry Department, University of Glasgow, Glasgow G12 8QQ Great Britain;Department of Chemistry, University of Western Ontario, London Canada N6A 5B7 |
| Abstract: | The complex Pt2Me2(μ-H)(μ-dppm)2]PF6] (I, dppm = Ph2PCH2PPh2) has been prepared and characterised by 1H and 31P NMR spectroscopy and by a full molecular structure determination by X-ray methods. The complex undergoes only slow reductive elimination of methane induced by added tertiary phosphine at 70°C. |
| Keywords: | Korrespondenzautor |
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