DC polarography: Effects of electrode sphericity on the current—Potential curves with EC and CE mechanisms |
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Authors: | J. Gálvez A. Molina T. Fuente |
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Affiliation: | Laboratory of Physical Chemistry, Faculty of Science, Murcia, Spain |
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Abstract: | Explicit equations which take into account the effect of sphericity of the DME on the current—potential curves with EC and CE mechanisms accompanied by Nernstian behavior have been derived in a rigorous way. These equations have been obtained without using the steady-state approximation and therefore they are valid without any limitation in the magnitude of rate constants of the chemical reaction. |
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