The insertion of the dioxides of carbon and sulphur into the palladium-carbon bond |
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Authors: | Trinh Hung P.W. Jolly G. Wilke |
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Affiliation: | Max-Planck-Institut für Kohlenforschung, Lembkestr. 5, D-4330 Mülheim a.d. Ruhr, W.-Germany |
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Abstract: | Bis ( η1, η2-allyl) palladium phosphine complexes react with carbon dioxide and sulphur dioxide by insertion into the palladium-carbon σ-bond to give η3-allylpalladium-carboxylate and -S-sulphinate complexes. |
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