Transition metal allyls : IV. The (η3-allyl)2M complexes of nickel,palladium and platinum: reaction with tertiary phosphines期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Transition metal allyls : IV. The (η3-allyl)2M complexes of nickel,palladium and platinum: reaction with tertiary phosphines

Authors:	B Henc PW Jolly R Salz S Stobbe G Wilke R Benn R Mynott K Seevogel R Goddard C Krüger

Institution:	Max-Planck-Institut für Kohlenforschung, D-4330 Mülheim a.d. Ruhr W.-Germany

Abstract:	A series of 1 : 1 adducts have been prepared by treating the bis-η³-allyl complexes of nickel, palladium and platinum with tertiary phosphines. Investigations of their structure in solution as well as in the crystal have shown that both 18-electron (η³-allyl)₂ML complexes as well as 16-electron (η¹-allyl)-(η³-allyl)ML complexes may be formed.

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