Hexa-, hepta- und octafluortrimethylamin |
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Authors: | H Bürger H Niepel G Pawelke HJ Frohn P Sartori |
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Institution: | Anorganische Chemie, FB 9, Gesamthochschule, D-5600 Wuppertal F.R.G.;Anorganische Chemie, FB 6, Gesamthochschule, D-4100 Duisburg F.R.G. |
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Abstract: | The electrofluorination of N(CH3)3 yields, along with fragmentation and recombination products and N(CF3)3 (I), minor quantities of the hitherto unknown compounds (CF3)2 NCF2H (II), CF3N(CF2H)2 (III) and N(CF2H)3 (IV). I –IV have been isolated and characterized by their 1H, 13C and 19F nmr and their E I and C I mass spectra. |
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