Nucleophilic reactions of fluoroolefins. I. Reactions of 1-(2-tetrahydrofuryl)-pentafluoropropene with alkoxide ions |
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Authors: | Wojciech Dmowski |
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Institution: | Institute of Organic Chemistry, Polish Academy of Sciences, 00-961, Warsaw, Poland |
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Abstract: | Unlike unsubstituted perfluoropropene 1,2] 1-(2-tetrahydrofuryl)-pentafluoropropene reacts with sodium alkoxides in parent alcohol solutions to give 1-alkoxy-1-(2-tetrahydrofuryl)-tetrafluoropropenes as major products and 1-alkoxy-2H-1-(2-tetrahydrofuryl)-pentafluoropropanes as very minor products. The yield of adducts is, to some extent, increased by the reduced basicity of the alkoxide ion. Results are discussed in terms of the supposed properties of the carbanionic intermediates involved.N.m.r., m.s., and i.r. data for, and some chemical properties of compounds , viz., further reactions with sodium alkoxides and hydrolysis are described. |
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