Zur Kenntnis der Chemie der Metallcarbonyle und der Cyano-Komplexe in flüssigem ammoniak : XL. Über die Reaktion kationischer Cyclopentadienyl-carbonyl-nitrosyl-Komplexe des Mangans und Rheniums mit flüssigem Ammoniak

The reactions of the cationic complexes CpMn(CO)₂NO]⁺, MeCpMn(CO)₂NO]⁺ (Cp = η⁵-C₅H₅, MeCp = η⁵-C₅H₄CH₃), CpRe(CO)₂NO]⁺, CpMn(CO)(L)NO]⁺ (L = PPh₃, PEt₂Ph, AsPh₃, CNMe, CNEt), {CpMn(CO)NO]₂Me₂PC₂H₄PMe₂}²⁺ and {CpMn(CO)NO]₂Ph₂PC₂H₄PPh₂}²⁺ with liquid NH₃ yield the neutral carbamoyl complexes CpMn(CO)(NO)CONH₂, MeCpMn(CO)(NO)CONH₂, CpRe(CO)(NO)CONH₂, CpMn(L)(NO)CONH₂ (L = PPh₃, PEt₂Ph, AsPh₃, CNMe, CNEt), CpMn(NO)CONH₂]₂Me₂PC₂H₄PMe₂ and CpMn(NO)CONH₂]₂Ph₂PC₂H₄PPh₂. Properties and reactions of these new compounds are described.