Novel sulfur-nitrogen-fluorine compounds : synthesis and properties of SF5NHF,SF5NClF and SF4NF |
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Authors: | Darryl D. DesMarteau |
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Affiliation: | Department of Chemistry, Kansas State University, Manhattan, Kansas 66506 USA |
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Abstract: | Using reactions developed for the synthesis of CF2NF, CF3NClF and CF3NHF from ClCN, F3SN can now be converted in high yield to the analogous sulfur compounds, SF4NF, SF5NClF and SF5NHF. N-fluorotetrafluorosulfurimine is the simplest sulfur(VI) imine and is a rigid molecule. Details on the synthesis and properties of these novel compounds will be presented. |
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