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Coupling of imidoyl chlorides to diazadienes by anionic nickel complexes |
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| Authors: | Holward Alper Masato Tanaka Khaled Hachem |
| Institution: | Department of Chemistry, University of Ottawa, Ottawa, Ontario K1N 9B4 Canada |
| Abstract: | Imidoyl chlorides react with aroyltricarbonylnickelates, under mild conditions, to give 1,4-diaza-1,3-butadienes and α-diketones. An electron transfer mechanism is proposed for this reaction. |
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