Mass spectrometry of π-complexes of transition metals XIX. Cymantrene-cyclopentadienylmetal carbonyl derivatives |
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| Authors: | V.F. Sizoi Yu.S. Nekrasov Yu.N. Sukharev L.I. Leontyeva S.A. Eremin N.E. Kolobova M.Ya. Solodova Z.P. Valueva |
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| Affiliation: | Institute of Organoelement compounds of the Academy of Sciences of the U.S.S.R., Vavilov st. 28, Moscow 117312 U.S.S.R. |
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| Abstract: | Mass spectra of the complexes π-C5H5M(CO)nXC5H4Mn(CO)3 have been studied. The presence of intense ions C5H5M(CO)nMn+ suggests that synthesis of new compounds with charged bivalent manganese of π-C5H5W(CO)3Mn+X? type is possible. In addition, the presence of these ions indicates preferential loss of the first three carbonyl groups from the manganese atom. |
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| Keywords: | Author for correspondence. |
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