Fluorocyclohexanes Part XIV [1] 1-H-decafluorocyclohexylamine |
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| Authors: | PL Coe JH Sleigh JC Tatlow |
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| Institution: | Department of Chemistry, University of Birmingham, P.O. Box 363, Birmingham B15 2TT Great Britain |
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| Abstract: | 1--Decafluorocyclohexylamine (V) has been prepared from decafluorocyclohexene (I). (I) gave the corresponding epoxide (II) by reaction with alkaline hydrogen peroxide, reaction of (II) with fluoride ion in sulpholane yielded decafluorocyclohexanone (III). This then gave decafluorocyclohexylidene imine (IV), lithium aluminium hydride reduction affording the desired 1--decafluorocyclohexylamine (V). |
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