Synthesis and structural characterization of cis-Pt(SH)2(PPh3)2 and related alkyl and aryl thiolato complexes |
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| Authors: | Clive E Briant Glyn R Hughes Peter C Minshall DMichael P Mingos |
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| Institution: | Inorganic Chemistry and Chemical Crystallography Laboratories, University of Oxford, South Parks Road, Oxford OX 3QR Great Britain |
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| Abstract: | The synthesis and spectroscopic characterization of the complexes cis-Pt(SR)2(PPh3)2 (R = H. Me, n-Bu and Ph) are reported, together with the single crystal X-ray crystallographic characterization of cis-Pt(SH)2(PPh3)2. The ability of these complexes to act as bidentate ligands towards other metal centres is also briefly described. |
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