Diorganostyrylzinndiorganophosphine und ihre tricarbonylnickel-komplexe |
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| Authors: | H Schumann G Rodewald JL Lefferts JJ Zuckerman |
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| Institution: | Institut für Anorganische und Analytische Chemie der Technischen Universität Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12 Deutschland;Department of Chemistry; University of Oklahoma, Norman, Oklahoma 73 019 U.S.A. |
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| Abstract: | Diorganostyryltin chlorides R2StySnCl (R = C4H9, p-CH3C6H4, R2 = (CH2)5) react with trimethylsilyl di-t-butylphosphine or trimethylsilyl diphenylphosphine to form trimethylchlorosilane and the corresponding diorganostyryltin-diorganophosphines, which can be separated and characterized by IR, NMR, Mössbauer and mass spectroscopy. With Ni(CO)4 the tin—phosphorus derivatives give diorganostyryltin diorganophosphinetricarbonylnickel complexes. |
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| Keywords: | Korrespondenzautor |
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