|
|||||
|
|
| 外电场下的TCNQ电子转移过程研究 | |
| 引用本文： | 张学亚,刘卓,陆国会,里佐威,高淑琴,李东飞,周密,门志伟,曹彪,欧阳顺利,杨健戈. 外电场下的TCNQ电子转移过程研究[J]. 光散射学报, 2009, 21(4): 355-359 |
| 作者姓名： | 张学亚 刘卓 陆国会 里佐威 高淑琴 李东飞 周密 门志伟 曹彪 欧阳顺利 杨健戈 |
| 作者单位： | 1. 吉林大学超硬材料国家重点实验室,长春 130021;吉林大学物理学院,长春 130023 2. 吉林大学物理学院,长春,130023 3. 吉林大学物理学院,长春 130023;空军航空大学航空军械系,长春 130022 |
| 摘 要： | 自制了紫外/拉曼两用的电化学薄层池。观测到了TCNQ在外电场作用下转变为TCNQ－而后又转变为TCNQ2－的紫外-可见吸收光谱变化的电子转移过程, 并且当有氧气存在时, TCNQ2－又被氧化而形成DCTC－的过程。还观测到了TCNQ在外电场作用下转变为TCNQ－的傅里叶变换拉曼光谱发生频移的电子转移过程。 |
| 关 键 词： | TCNQ 电子转移 电化学 |
| 收稿时间： | 2009-04-15 |
The Electron Transfer Process Research of the TCNQ in Outside Electric Field |
|
| ZHANG Xue-ya,LIU Zhuo,LU Guo-hui,LI Zuo-wei,GA Shu-qin,LI Dong-fei,ZHOU Mi,MEN Zhi-wei,CAO Biao,OUYANG Shun-li,YANG Jian-ge. The Electron Transfer Process Research of the TCNQ in Outside Electric Field[J]. Chinese Journal of Light Scattering, 2009, 21(4): 355-359 | |
| Authors: | ZHANG Xue-ya LIU Zhuo LU Guo-hui LI Zuo-wei GA Shu-qin LI Dong-fei ZHOU Mi MEN Zhi-wei CAO Biao OUYANG Shun-li YANG Jian-ge |
| Affiliation: | ZHANG Xue-ya1,2,LIU Zhuo2,LU Guo-hui2,LI Zuo-wei1,GAO Shu-qin2,LI Dong-fei2,ZHOU Mi2,MEN Zhi-wei2,CAO Biao2,OU-YANG Shun-li2,YANG Jian-ge2,3(1.State Key Laboratory of Superhard Materials,Jilin University,Changchun 130021,China,2.Department of Physics,Changchun 130023,3.The Ordnance Engineering Department,Air Force Aviation University,Changchun 130022,China) |
| Abstract: | The coulometry cell is used by UV/Raman was made by ourselves.Electronic absorption spectra have been obtained for the electron transfer process of TCNQ.The Electronic absorption spectra changed for TCNQtransformed toTCNQ-,then transformed toTCNQ2-,and when oxygen exists,TCNQ2-was oxidized to DCTC-in outside electric field.And Fourier Transform Raman shift have been observed for the electron transfer process of the TCNQ changed into TCNQ-under the effect of outside electric field. |
| Keywords: | TCNQ TCNQ electron transrer electrochemistry |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |