Proton transfer versus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes |
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| Authors: | Carroll Joseph B Gray Mark Cooke Graeme Rotello Vincent M |
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| Institution: | Department of Chemistry, The University of Massachusetts, Amherst, MA 01003, USA. |
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| Abstract: | Phenanthrenequinone undergoes highly efficient proton transfer processes in the presence of a thiourea-functionalised polystyrene copolymer whereas interactions with a similar benzyl-thiourea monomer show strong redox modulation of the quinone without proton transfer. |
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