Generation of strong, homochiral bases by electrochemical reduction of phenazine derivatives |
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| Authors: | Alonso A Mateo Horcajada Roberto Groombridge Helen J Mandalia Reshma Motevalli Majid Utley James H P Wyatt Peter B |
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| Institution: | Department of Chemistry, Queen Mary, University of London, Mile End Road, London E1 4NS, UK. |
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| Abstract: | Electrochemical reduction of enantiomerically pure amino- and alkoxy-phenazine derivatives forms strongly basic radical anions which give asymmetric induction in the conversion of 3,4-epoxytetrahydrothiophene-1,1-dioxide into the allylic ester with facile regeneration of the phenazine. |
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