Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides |
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| Authors: | Ugrinova Vesela Ellis Gregory A Brown Seth N |
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| Affiliation: | Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, IN 46556-5670, USA. |
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| Abstract: | The monomeric titanium(IV) hydroxide complex, LTi(OH)(LH(3)= tris(2-hydroxy-3,5-di-tert-butylbenzyl)amine), which is sterically inhibited from condensation to a mu-oxo dimer, cannot be prepared by hydrolysis of the alkoxide, with K(eq)= 0.012 for hydrolysis of the titanium methoxide in THF. |
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