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The Ground and First Excited Torsional States of Acetic Acid
Authors:Ilyushin V V  Alekseev E A  Dyubko S F  Podnos S V  Kleiner I  Margulès L  Wlodarczak G  Demaison J  Cosléou J  Maté B  Karyakin E N  Golubiatnikov G Yu  Fraser G T  Suenram R D  Hougen J T
Institution:Institute of Radio Astronomy of NASU, Krasnoznamennaya 4, Kharkov, 310002, Ukraine
Abstract:A global fit of microwave and millimeter-wave rotational transitions in the ground and first excited torsional states (v(t) = 0 and 1) of acetic acid (CH(3)COOH) is reported, which combines older measurements from the literature with new measurements from Kharkov, Lille, and NIST. The fit uses a model developed initially for acetaldehyde and methanol-type internal rotor molecules. It requires 34 parameters to achieve a unitless weighted standard deviation of 0.84 for a total of 2518 data and includes A- and E-species transitions with J
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