1H NMR study of the phase behavior of aqueous eutectic solutions using the inverse Laplace transform analysis of T2 relaxation |
| |
| Authors: | Jessi A. Baughman G. Joseph Ray Szabo M. Christina Jane O. Werling Peter L. Rinaldi |
| |
| Affiliation: | 1. Department of Chemistry, University of Akron, Akron, OH, United States;2. Research and Development, Baxter Healthcare Corp, Round Lake, IL, United States |
| |
| Abstract: | High‐field 1H NMR T2 relaxation studies were used to characterize the changes in the physical phases of water, NaCl, and dextrose solutions over a temperature range of ?65 to 15 °C. The data were analyzed with the inverse Laplace transform and with a linear fit to the logarithm of the time domain signal. Two liquid phases were detected for the NaCl and dextrose solutions at lower temperatures and assigned to low and high concentrated solution domains. The high concentrated solution domain was found to be present between ?30 and ?5 °C in the NaCl solution and between ?55 and ?5 °C in the dextrose solution. Copyright © 2017 John Wiley & Sons, Ltd. |
| |
| Keywords: | NMR time domain NMR frequency domain NMR inverse Laplace Transform eutectic solutions variable temperature |
|
|
