Chelating diphos ligands with inorganic backbones. Crystal structure of [PtCl2{(PPh2O)2SiPh2}]期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Chelating diphos ligands with inorganic backbones. Crystal structure of [PtCl₂{(PPh₂O)₂SiPh₂}]

Authors:	John K Hogg Stuart L James A Guy Orpen Paul G Pringle

Institution:	Fakultät für Chemie der Universität Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld Deutschland

Abstract:	The metallo-phosphaalkenes (η⁵-C₅Me₅)(CO)₂FeP=C(R)(SiMe₃) (Ia: R = SiMe₃, Ib: R = Ph) and MeO₂C---CC---CO₂Me undergo a dipolar 3+2]-cycloaddition to afford the metallo-heterocycles (η⁵-C₅Me₅)(CO) Full-size image =C(R)SiMe₃] (IIIa,b) with exocyclic P=C double bonds.

Keywords:	Platinum Silicon Chelate Phosphinite Crystal structure
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