Oxidation of Hydrogen on Complexes of Platinum and Palladium with N-Allyl-N´-propylthiourea Immobilized on Silica Surfaces |
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Authors: | Yatsimirskii V. K. Boldyreva O. Yu. |
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Affiliation: | (1) Taras Shevchenko Kyiv National University, 64 Volodymyrs'ka Vul., 01033 Kyiv, Ukraine |
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Abstract: | Complexes of platinum and palladium with N-allyl-N´-propylthiourea immobilized on an SiO2 surface have high catalytic activity in the oxidation of hydrogen in the temperature range 273-373 K after partial destruction of the ligand. The kinetics of the oxidation of hydrogen is in accord with the Eley–Rideal mechanism. |
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