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Remote substituent effects on the photooxygenation of 9,10-diarylanthracenes: strong evidence for polar intermediates
Authors:Fudickar Werner  Linker Torsten
Affiliation:Department of Chemistry, University of Potsdam, Karl-Liebknecht Str. 24-25, D-14476, Potsdam/Golm, Germany.
Abstract:Two different reaction pathways in the photooxygenation of 9,10-diarylanthracenes are identified, with strong evidence for polar (forward, singlet oxygen addition) and radical (backward, thermolysis) intermediates.
Keywords:
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