Derivatives of phosphorous acid as a new class of ligands for Pd-catalyzed allylation |
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| Authors: | Moiseev S K Lebedev R V Polosukhin A I Kalinin V N |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Amido- and aminophosphites and hydrospirophosphoranes can be used as ligands in the Pd-catalyzed allylation of ethyl malonate with ethyl (3-phenylprop-2-enyl) carbonate. Bidentate ligands (RO)2P--O(CH2)n--NR"2 (n = 2 and 3) were found to be the most effective ligands. |
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| Keywords: | allylation palladium P N-ligands aminophosphites |
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