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C(sp)-C(sp3) bond formation through Cu-catalyzed cross-coupling of N-tosylhydrazones and trialkylsilylethynes
Authors:Ye Fei  Ma Xiaoshen  Xiao Qing  Li Huan  Zhang Yan  Wang Jianbo
Affiliation:Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing 100871, China.
Abstract:Copper-catalyzed cross-coupling of N-tosylhydrazones with trialkylsilylethynes leads to the formation of C(sp)-C(sp(3)) bonds. Cu carbene migratory insertion is proposed to play the key role in this transformation.
Keywords:
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