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Chloro(2‐{[5‐(2‐hydroxy­benzyl‐O)‐1,5‐di­aza‐1‐cyclo­octyl‐N,N′]­methyl}phenolato‐O)­cadmium(II)
Authors:Miao Du  Lin‐Hong Weng  Xue‐Bing Leng  Xian‐He Bu  Ruo‐Hua Zhang
Abstract:The crystal structure of the title complex, Cd(C20H25­N2­O2)­Cl], reveals a hydrogen‐bonded dimer composed of neutral molecules. The CdII center is five‐coordinated by two O atoms of the pendant arms, two nitro­gen donors of the 1,5‐di­aza­cyclo­octane ring and a chloride anion. The coordination geometry of the complex could be described as a distorted square pyramid. The 1,5‐di­aza­cyclo­octane backbone adopts a boat/chair configuration and the two phenol/phenolato groups have a dihedral angle of 101.3 (2)° between them. The coordinated phenolate and phenolic groups of inversion‐related mol­ecules form strong intermolecular O—H?O hydrogen bonds.
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