Abstract: | In the title complex, [Zn(C6H4FN2O4)2(H2O)4]·4H2O, the Zn atom is located at a center of symmetry and has a distorted octahedral geometry, with Zn—O distances in the range 2.052 (2)–2.181 (2) Å. Hydrogen bonds involving the water molecules make up a three‐dimensional network. |